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This volume gives background knowledge about the difficult matter of electrochemical behaviour of glass melts and solid glasses, laying the foundations for- a sound understanding of physicochemical redox and ion transfer processes in solid or liquid glasses and the interpretation of experimental results;- control of production processes, including fining, interface reactions and thermodynamic equilibria of glass melts with refractories and the surrounding atmosphere;- the field-driven ion exchange between solutions and glasses or within electrochromic thin-film systems; - fundamentals and application of glass electrodes for PH measurements, as well as information about the presently ongoing redefinition by a IUPAC committee;- mechanisms responsible for glass corrosion;- the concept of optical basicity.