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This classic introductory textbook provides a thorough introduction to the area of physical polymer science, emphasizing interrelationships between molecular structure and the morphology and mechanical behavior of polymers. With an increased focus on practical applications in polymer engineering and strong coverage of modern topics such as green polymers, biopolymers, light emitting polymers, and electrically conducting polymers, the Fifth Edition continues in the tradition of providing the basic concepts in an authoritative, technically correct, and current fashion. Its large number of worked examples and study problems make this book an ideal teaching text.