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Quantum Solids and Orderability. Volume 4 of the 5-volume Quantum Nanochemistry covers quantum physical chemical theory of solids and orderability and addresses the electronic order problems in the solid state viewed as a huge molecule in special quantum states, including also the bondonic treatment of the graphene nano-ribbons, along basic crystallographic principles, from geometrical-, to chemical- to physical- x-ray crystallography with featured examples, and energetic correlating symmetry discussion on orderability in nanochemical compounds.