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This book deals with the electrochemical studies on§the adsorption§behaviour of some sulphur containing organic§compounds mainly self-assembled§monolayers (SAMs) of alkanethiol and alkanethiol§derivatives on§gold surfaces. More specifically, this book focuses§on the§effect of different solvents§on the structure, integrity and interfacial§properties of different organic thiol§monolayers like alkanethiol, aliphatic and aromatic§dithiol, hydroxy and§carboxylic acid thiol and thiocholesterol.This book§also introduces the concept of "hydrophobic gap" at§the alkanethiol SAM-water interface due to drying§transition. The experimental observation based on§double-layer capacitance measurement and Scanning§tunneling microscope (STM) study supports the§Lum-Chandler-Weeks (LCW) theory on hydrophobicity.
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