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Solar energy will no doubt become a main source of energy in our society by the end of this century, but how big a role will photovoltaics play in this new energy infrastructure? There are fundamental bottlenecks and roadblocks for current photovoltaic technologies to become a noticeable source of energy: material availability, energy input, storage, recycling, cost, efficiency, and many societal issues such as public acceptance, government support, tax incentives, policy and legislation, among others. This book will analyse some of the non-societal barriers to large-scale deployment of photovoltaics in quantitative details. The book will also identify several strategic research directions to remove some of these barriers.